TY - CONF KW - Thermal conductivity KW - Electrical conductivity of other crystalline inorganic semiconductors [A7280J] KW - Thermoelectric effects (semiconductors/insulators) [A7220P] KW - thermoelectric figure of merit KW - Ge-Si alloys KW - Thermoelectric effects in semiconductors and insulators KW - acoustic phonon scattering KW - heavily doped semiconductor KW - Heavily doped semiconductors KW - high temperature transport properties KW - hole-phonon scattering KW - holes KW - ionized impurity scattering KW - large grain size KW - long-wavelength phonons KW - phonon scattering mechanism KW - phonon-phonon KW - point defect KW - Si-Ge KW - weak scattering AU - Cronin Vining AB - A model is presented for the high temperature transport properties of large grain size, heavily doped p-type silicon-germanium alloys. Good agreement with experiment (+or-10%) is found by considering acoustic phonon and ionized impurity scattering for holes and phonon-phonon, point defect and hole-phonon scattering for phonons. Phonon scattering by holes is found to be substantially weaker than phonon scattering by electrons, which accounts for the larger thermal conductivity values of p-type silicon-germanium alloys compared to similarly doped n-type silicon-germanium alloys. The relatively weak scattering of long-wavelength phonons by holes raises the possibility that p-type silicon-germanium alloys may be improved for thermoelectric applications by the addition of an additional phonon scattering mechanism which is effective on intermediate and long-wavelength phonons. Calculations indicate improvements in the thermoelectric figure of merit up to 40% may be possible by incorporating several volume percent of 20AA radius inclusions into p-type silicon-germanium alloys. (27 References). BT - Modern Perspectives on Thermoelectrics and Related Materials C1 - Anaheim, CA, USA. Mater. Res. Soc. 1-2 May 1991.EnglishConference Paper DA - 1991/// LA - eng N2 - A model is presented for the high temperature transport properties of large grain size, heavily doped p-type silicon-germanium alloys. Good agreement with experiment (+or-10%) is found by considering acoustic phonon and ionized impurity scattering for holes and phonon-phonon, point defect and hole-phonon scattering for phonons. Phonon scattering by holes is found to be substantially weaker than phonon scattering by electrons, which accounts for the larger thermal conductivity values of p-type silicon-germanium alloys compared to similarly doped n-type silicon-germanium alloys. The relatively weak scattering of long-wavelength phonons by holes raises the possibility that p-type silicon-germanium alloys may be improved for thermoelectric applications by the addition of an additional phonon scattering mechanism which is effective on intermediate and long-wavelength phonons. Calculations indicate improvements in the thermoelectric figure of merit up to 40% may be possible by incorporating several volume percent of 20AA radius inclusions into p-type silicon-germanium alloys. (27 References). PB - Mater. Res. Soc. PY - 1991 SP - 95 EP - 104 EP - T2 - Modern Perspectives on Thermoelectrics and Related Materials TI - A model for the high temperature transport properties of heavily doped p-type silicon-germanium alloys UR - http://cvining.com/system/files/articles/vining/Vining-MRS234-1991.pdf VL - 234 ER -